30％TBP-煤油中亚硝酸同铀(Ⅳ)和硝酸的反应

REACTION OF NITROUS ACID WITH U(Ⅳ) AND NITRIC ACID IN 30% TBPKEROSENE SOLUTION

摘要: 文章研究了TBP相亚硝酸同轴(IV)和硝酸的反应,通过实验,求得亚硝酸氧化铀(IV)和亚硝酸与硝酸反应速率的经验式,它们分别为: -d[U(IV)]/(dt)=0.14[U(IV)][HNO_2]~(0.55)/[NHO_3]~(0.43) 和-(d[NHO_2]/(dt))_消=0.16[HNO_2][HNO_3]亚硝酸的变化速率为: d[HNO_2]/(dt)=0.14[U(IV)][HNO_2]~(0.55)/[HNO_3]~(0.43)-0.16[HNO_2][HNO_3]
- 亚硝酸 ,
- 铀 ,
- TBP ,
- 速率方程
Abstract: Reaction of nitrous acid with U(IV) and nitric acid in 30% TBP-kerosene solution is investigated, the rate equations of oxidation of U(IV) bynitrous acid and that of nitrous acid reacting with nitric acid can be expressed as:-d[U(IV)]/dt=0.14[U(IV)][HNO_2]~(0.55)/[HNO_3]~(0.43)and-d[HNO_2]/dt=0.16[HNO_2][HNO_3]respectively, and the overall reaction rate equation for nitrous acid is:d[HNO_2]/dt=0.14 [U(IV)][HNO_2]~(0.55)/LHNO_3]~(0.43)-0.16[HNO_2][HNO_3]
- Nitrous acid ,
- ,
- Uranium ,

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