QIAN HESHENG;XIA YUANXIAN Shanghai Institute of Nuclear Research, Academia Sinica. DIRECT SPECTROPHOTOMETRIC DETERMINATION OF THORIUM IN ORGANIC PHASE BY CHLOROPHOSPHONAZO-mA[J]. Atomic Energy Science and Technology, 1986, 20(3): 302-302. DOI: 10.7538/yzk.1986.20.03.0302
Citation: QIAN HESHENG;XIA YUANXIAN Shanghai Institute of Nuclear Research, Academia Sinica. DIRECT SPECTROPHOTOMETRIC DETERMINATION OF THORIUM IN ORGANIC PHASE BY CHLOROPHOSPHONAZO-mA[J]. Atomic Energy Science and Technology, 1986, 20(3): 302-302. DOI: 10.7538/yzk.1986.20.03.0302

DIRECT SPECTROPHOTOMETRIC DETERMINATION OF THORIUM IN ORGANIC PHASE BY CHLOROPHOSPHONAZO-mA

  • The method of the determination of trace amount of thorium in the extractionprocess of thorium has been investigated. In acidic medium, chlorophosphonazo--mAreacts with thorium ion to form a purple colour complex. With ethylene glycol mo-nobutyl ether as solvent, thorium in the organic phase can be directly determined.Under the experimental conditions employed, the apparent molar absorptivity ofthorium at 670nm is 1×10~5. Beer's law is obeyed for 0--12 μg of thorium.
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