Neutron Powder Diffraction Study of La1-xCaxMn0.96Fe0.04O3（x=0.31,0.5,0.6）

ZHANG Li; XUE Yan-jie; ZHANG Bai-sheng; CHEN Na; CHEN Dong-feng; CHENG Zhao-hua; LU Yi; LI Qing-an; DI Nai-li

doi:10.7538/yzk.2006.40.04.0402

ZHANG Li, XUE Yan-jie, ZHANG Bai-sheng, CHEN Na, CHEN Dong-feng, CHENG Zhao-hua, LU Yi, LI Qing-an, DI Nai-li. Neutron Powder Diffraction Study of La1-xCaxMn0.96Fe0.04O3（x=0.31,0.5,0.6）[J]. Atomic Energy Science and Technology, 2006, 40(4): 402-405. DOI: 10.7538/yzk.2006.40.04.0402

Citation:

Neutron Powder Diffraction Study of La_1-xCaxMn_0.96Fe_0.04O₃（x=0.31,0.5,0.6）

Graphical Abstract

Graphical Abstract

Abstract

Abstract

The crystallographic structures of perovskite manganites La_1-xCa_xMn_0.96Fe_0.04O₃（x=0.31,0.5,0.6） were refined by Rietveld analysis of neutron diffraction data at room temperature. The refined results indicate that La_1-xCa_xMn_0.96Fe_0.04O₃（x=0.31,0.5,0.6） compound has MnO₆ type (space group: Pnma) octahedral shape. The La/Ca atoms prefer to 4c sites, the Mn/Fe atoms prefer to 4b sites, and the O atoms prefer to 4c and 8d sites. The Mn-O bond distances and the Mn-O-Mn angles were obtained. The relationship between magnetic properties and structures is discussed.

FullText(HTML)

References (9)

Cited By

Turn off MathJax

Article Contents

Neutron Powder Diffraction Study of La1-xCaxMn0.96Fe0.04O3（x=0.31,0.5,0.6）

Graphical Abstract

Abstract

Catalog

Export File

Citation

Format

Content

Neutron Powder Diffraction Study of La_1-xCaxMn_0.96Fe_0.04O₃（x=0.31,0.5,0.6）