XIA Wen, YE Hong-sheng, XU Li-jun, LIN Min, JIN Xiao-feng, CHEN Yi-zhen, CHEN Ke-sheng. Synthesis and Extractive Property Evaluation of 1-phenyl-3-methyl-4-caprylpyrazolone-5[J]. Atomic Energy Science and Technology, 2008, 42(z1): 88-91. DOI: 10.7538/yzk.2008.42.z1.0088
Citation: XIA Wen, YE Hong-sheng, XU Li-jun, LIN Min, JIN Xiao-feng, CHEN Yi-zhen, CHEN Ke-sheng. Synthesis and Extractive Property Evaluation of 1-phenyl-3-methyl-4-caprylpyrazolone-5[J]. Atomic Energy Science and Technology, 2008, 42(z1): 88-91. DOI: 10.7538/yzk.2008.42.z1.0088

Synthesis and Extractive Property Evaluation of 1-phenyl-3-methyl-4-caprylpyrazolone-5

  • 1-phenyl-3-methyl-4-caprylpyrazolone-5(PMCyP) was synthesized from 1-phenyl-3-methyl-pyrazolone-5 (PMP) and caprylyl chloride, and some extraction parameters were investigated such as the acidity, the concentration of Sr, the time of the extraction and the thinners. 5 g/L PMCyP-MIBK, pH=9.0 and 1 min of extraction are testified the best condition. The final solution of Sr is stored in 0.1 mol/L hydrochloric acid. Strontium and yttrium can be separated by changing the acidity, and it can be used to separate the radioactive Sr from matrix. The saturation of 10 mL 1 g/L PMCyP-MIBK is about 1 mg, and the stoichiometric proportion to Sr is 3∶1 in extraction.
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