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WANG Zhe, OUYANG Ying-gen, WANG Chang-shui, SHI Hu-xin, ZHENG Hai-yang. Research of Electrochemical Behavior of Thorium in LiCl-KCl Melts[J]. Atomic Energy Science and Technology, 2012, 46(增刊): 180-183. DOI: 10.7538/yzk.2012.46.suppl.0180
Citation: WANG Zhe, OUYANG Ying-gen, WANG Chang-shui, SHI Hu-xin, ZHENG Hai-yang. Research of Electrochemical Behavior of Thorium in LiCl-KCl Melts[J]. Atomic Energy Science and Technology, 2012, 46(增刊): 180-183. DOI: 10.7538/yzk.2012.46.suppl.0180
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Research of Electrochemical Behavior of Thorium in LiCl-KCl Melts

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  • The electrochemical process on the Mo cathode of Th4+ ion in the LiCl-KCl melts was studied by the cyclic voltammetry and chronopotentiometry. The results of research show that the electrode process is controlled by diffusion and the temperature dependence of diffusion coefficient D can be described by ln D＝33.94-2.879×104/T. The apparent potential is E vsCl-0/Cl2＝-3.45+7.5×10-4T.
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