热诱导倒相法硅掺杂PMP泡沫的研制

Preparation of Si Doped Poly(4 methyl-1-pentene) Foams by Thermal Induced Phase-inversion Technique

  • 摘要: 研究了核聚变靶材硅 (Si)掺杂聚 4 甲基 1 戊烯 (PMP)泡沫热诱导倒相法的制备工艺及影响泡沫材料结构与性能的主要因素。确定了均四甲苯 /萘 (质量比约为 60∶40 )为适宜的二元溶剂体系及体系各组分配比与产品泡沫密度关系的工作曲线。热重 差热分析结果表明 :掺硅PMP泡沫的热稳定性与密度间存在明显的依赖关系, 随着PMP泡沫密度降低, 材料的起始裂解温度升高, 裂解焓减少。经实验研究, 首次用热诱导倒相法成功制得了密度为 5~ 80mg/cm-3 、含硅量ω(Si)≤ 1%、孔径 1~ 2 0 μm的硅掺杂PMP泡沫材料。

     

    Abstract: With poly(4 methyl 1 pentene)(PMP) as the foam skeleton material, durene/naphthalene as the solvent/non solvent system and silicon containing polymer as the doping material, Si doped CH polymer foams are successfully prepared with the density of 5~ 80 mg/cm 3, and the mass percentage of Si in the foams is less than 1%. The paper presents the fabrication procedures of Si doped CH polymer foams, and the parameters which influence the properties of the foam products are discussed in detail. The thermal analytical technique(TG DSC) is used to measure the foam's thermal properties. It is found that the foam's thermal stability varies with it's density.

     

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