Abstract:
The crud occurred in Purex process is caused by the degradations of extractant and solvent and the existence of insoluble solid particle in the nuclear fuel reprocessing. The crud seriously affects the operation of the extraction column. The present (paper) reviews the study status on the crud in the Purex process. It is generally accepted that in the Purex process, particularly in the first cycle, the crud occurrence is related to the capillary chemistry phenomena resulting from the deposits of Zr with TBP degradation products HDBP, H_2MBP, H_3PO_4 and the insoluble particle RuO_2 and Pd. The occurrence of deposits and the type of crud are tightly related to the molar ratio of HDBP and Zr, and the aqueous pH. In addition, the effect of degradation products from the diluent, such as kerosene, is an unnegligible factor to cause the crud. The crud can be discharged from the extraction equipment with Na_2CO_3 or oxalic acid. In the study on simulating the crud, the effects of the deposits of Zr with TBP degradation products HDBP, H_2MBP and H_3PO_4, and the insoluble particle RuO_2 and Pd should be considered at the same time.