全体积R7T7型参考玻璃固化体裂隙初步研究

Preliminary Study of Fractured Full Scale Inactive R7T7 Type Glass

  • 摘要: 为从微观角度研究裂隙对玻璃固化体腐蚀影响,引入体视学方法对玻璃体裂隙进行了裂隙分布、腐蚀程度等初步研究。采用扫描电镜对结束1 147 d静态浸出实验后的全体积R7T7型参考玻璃的部分样品进行分析。根据分析得到的二维参数,通过体视学方法计算得到全体积玻璃体的裂隙率FR为41±13,腐蚀量为(3.88±1.20)×10-4m3,约占玻璃体参与水相腐蚀反应总体积的(0.28±0.09)%。分析还发现,裂隙腐蚀产物厚度小于10 μm的裂隙占裂隙总数的80%,这些裂隙导致的腐蚀仅占总腐蚀表面积的30%;同时,腐蚀产物厚度大于10 μm的裂隙对样品总腐蚀表面积贡献了70%。

     

    Abstract: During vitrified industry process, the melted glass will be fractured after it is poured into the canister. When this fractured glass is disposed in deep geological media, it will be altered for contacting aqueous solution. Glass alteration involves several mechanisms, applied to a reactive surface area that must be accurately determined. This will allow computing the quantities of altered glass and the amount of radionuclides released from the package depending on the environmental conditions. This work researched a fractured full scale glass block after 1 147 d static leaching test at 90 ℃. Through a stereological approach, the fracture ratio of the full scale glass block is estimated to 41±13. About (3.88±1.20)×10-4m3 glass volume equating (0.28±0.09)% of the full glass block were altered. These calculations are consistent with the data obtained from the leaching solution. It is also found that most of the cracks (>80%) had a gel layer less than 10 μm thick. This kind of cracks led to only 30% of the total alteration surface. On the other hand, the cracks whose gel layer thickness are larger than 10 μm, and play a major role on the global alteration. The results of this work are in good agreement with those from archaeological glass blocks.

     

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