用AFM分析魔芋辐照接枝聚合物的构效关系

AFM Analysis of Copolymer From Konjac With Acrylic Acid by γ Irradiation

  • 摘要: 研究了魔芋粉、魔芋辐照接枝聚合物及聚合物的再生产物的吸水特性,并对三者的三维表面形貌进行了原子力显微镜分析,以探索吸水性能与结构改变的相关关系。研究结果表明,改性后魔芋吸水倍数、速度和保水率随颗粒的细化和吸收液离子浓度的下降而上升,保水率还随环境温度的上升和胶体水分缓释时间的延长而下降。改性魔芋蒸馏水和自来水最大吸收倍数分别达887和273;最快吸收速度分别为64.7和27.6 g•g-1•min-1;充分吸胀蒸馏水和自来水后胶体24 h最大保水率分别达92%和84%。AFM分析表明,魔芋与丙烯酸接枝后,形成了更多的亲水键,吸水倍数剧增,魔芋聚合物吸水后再生过程中,晶体发生了重排,三维网状结构向亲水性方面倾斜,吸水倍数较其本身进一步提高,吸水倍数最大达360。

     

    Abstract: The water absorption property and atomic force microscopy (AFM) analysis were studied to discover the relativity of water absorption and construction of original konjac powder, grafted copolymer and regenerator. The results show that the water absorption, speed and reserving percent of the grafted copolymer are affected by the size, the liquid ion concentration, the ambient temperature and water reserving time of the gel. At room temperature, the largest water absorption, water absorption speed and water reserving percent of grafted copolymer are 887 times, 64.7 g•g-1•min-1 and 92% in distilled water and 273 times, 27.6 g•g-1•min-1 and 84% in tap water respectively. The AFM images of grafted copolymer indicate that konjac grafts acrylic acid and then hydrophilic structure comes into being. During the course of regeneration the three dimensional structure of the copolymer was changed to more regularly. So the water absorption of copolymer is higher than that of konjac, and the water absorption of regenerator is 360 times, higher than that of copolymer.

     

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