超细钨丝连续电解抛光工艺参数优化

Optimization of Technological Parameters of Continuous Electrochemical Corrosion for Ultra-fine Tungsten Wire Preparation

  • 摘要: 以直径低于10 μm的超细钨丝作为Z-pinch实验丝阵负载材料,其制备常用到电解腐蚀技术。为定量控制每道次钨丝的减径量,并探索钨丝电解参数优化方法,根据法拉第定律推导并验证了在应用电解腐蚀技术制备超细钨丝的过程中单位长度钨丝的失重与电流强度和拉丝速率的比值存在正比关系。实验观测到,道次减径比超过25%时,断丝几率较减径比为20%时的高60%以上。基于实验结论,提出了每道次定量控制钨丝直径减少量的方法。在18~26 ℃、质量分数为15%的KOH溶液中,针对3 μm 钨丝采用了最小化腐蚀道次的电解参数。对用这种参数制得的钨丝进行SEM和力学性能测试,结果表明,钨丝表面质量与断裂强度更好。

     

    Abstract: Electrochemical corrosion technology is usually employed to prepare ultra-fine tungsten wires with the diameter less than 10 μm, which are used as materials of wire arrays for Z-pinch tests. For quantitatively controlling diameter reduction of tungsten wire in a certain pass, and exploring the ways to optimize electrolytic parameters according to Faraday law, the relationship of direct ratio between loss weight of tungsten wire and the ratio of current intensity through it and coiling velocity in the process of ultra-fine tungsten wire producing using electrochemical corrosion technology was deduced and examined. It is found that when the percentage of diameter reduction in a certain pass exceeds 25%, the probability of wire breakdown increases above 60%, relative to that of 20% diameter reduction. Based on such conclusion, the way of quantitative control of diameter reduction of tungsten wire in a certain pass was pointed out. And during 18 and 26 ℃, in the KOH solution with 15 mass percent, electrolytic parameters for minimizing corrosion passes were employed aiming at 3 μm tungsten wire producing. Tungsten wire produced under such optimizing conditions is found better performances in surface quality and break-down strength after tests of SEM and mechanical property.

     

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