α-CxNy:H1-x-y薄膜的制备和光学性能分析

Preparation and Optical Properties of α-CxNy:H1-x-y Films

  • 摘要: 采用外置式电容耦合低压等离子体化学气相沉积法,以高纯CH4/N2/H2作为反应气体,制备非晶α-CxNy:H1-x-y薄膜。研究了薄膜沉积速率和入射功率之间的关系,随着功率增大,薄膜沉积速率先增大后减小;SEM图像表明薄膜无层状、柱状结构;AFM图像表明薄膜粗糙度在0.2~0.3 nm之间;傅里叶红外光谱(FTIR)显示了薄膜的成键情况;紫外可见近红外光谱表明,随着入射功率的增大,薄膜的光学带隙逐渐减小。

     

    Abstract: Amorphous hydrogenated carbon nitride thin films (α-CxNy:H1-x-y) were synthesized by external capacitive coupling low pressure plasma chemical vapor deposition (LPPCVD) with CH4, N2 and H2 gases. The deposition rate and optical properties of the deposited CHN films were systematically analyzed as a function of radio power. The morphology of the films was investigated by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The chemical structure and elemental composition of the CHN films were characterized by Fourier transform infrared spectroscopy ( FTIR). The FTIR investigation demonstrates the presence of carbon-nitrogen bonds with hydrogenated components in the films. And its optical gap ranges from 1.953-2.359 eV, and the optical gap becomes narrower with the incident power increasing.

     

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