核级石墨氧化腐蚀模型研究

Study on Model of Nuclear Graphite Oxidation

  • 摘要: 高温气冷堆内应用到大量核级石墨材料,对其长期氧化腐蚀行为进行研究至关重要。文章建立了综合考虑石墨内部孔隙率变化及失重率影响的石墨氧化模型,对气体在石墨内部的瞬时氧化腐蚀情况进行了模拟计算。提出氧化深度的概念,研究发现反应温度越高,反应气体在石墨内部的氧化深度越小;并与实验结果及其他模型的计算结果进行了对比,验证了模型的有效性。

     

    Abstract: There are huge amounts of nuclear graphite serving as structural material in high temperature gas-cooled reactors (HTGRs). It is essential to study the long-term corrosion behavior of the graphite materials in core. A reasonable oxidation model considering the effects of porosity changing and the burn-off was established. Using the model, the transient oxidation behaviors of a semi-infinite graphite slab and a finite graphite tube were analyzed. It is found the oxidation depths decrease with the temperature increasing. The simulation results were also compared with the experimental results and calculation results in literature to verify the effectiveness of the oxidation model.

     

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