Abstract: The general corrosion behavior of three candidate materials （347, HR3C and In-718） was investigated in 650 ℃/25 MPa deionized water. Morphology and composition of the surface oxide film with different exposure time were observed through FEG-SEM and EDS. The phase constitute was analyzed by GIXRD. For all the test materials, the weight loss follows typical parabolic law and the weight loss of 347 shows more than 40 times higher than that of HR3C and In-718. The oxide film of three alloys mainly consists of Ni(Cr, Fe)₂O₄. In-718 shows severe pitting and the oxide film of 347 appears significant spalling, while HR3C has compact oxide film. In the high temperature supercritical water, the high Cr content may enhance the general corrosion property of the alloys, while addition of Nb may be detrimental to the pitting resistance of alloys.