Abstract: A self-indicating radiation personal dosimeter was investigated using radiation sensitive material diacetylene monomer PCDA, which was a component of the polymerization system. The substrate material, solvent, sensitive material, solution temperature, thickness of film and the preparation method were studied. The dosimeter colour changes from white to blue when exposed 0.1-2.5 Gy, and the linearly dependent coefficient of the exposure response is 0.999 8, the stability of absorbency in two weeks after exposure is testified well. It can be used as self-indicating radiation alert personal dosimeter.