镍基合金825在超临界水中的腐蚀性能研究

Corrosion Behavior of Nickel Based Alloy 825 in Supercritical Water

  • 摘要: 研究了镍基合金825在550 ℃/25 MPa、600 ℃/25 MPa和650 ℃/25 MPa超临界水(SCW)中的应力腐蚀开裂敏感性,以及在超临界650 ℃/25 MPa、次临界290 ℃/15.2 MPa水中的均匀腐蚀性能。通过慢应变速率拉伸实验得到了相应的应力-应变曲线,结果表明,随温度的升高,825的机械强度和塑性逐渐下降;实验后试样的SEM图像表明,825在3种工况下的应力腐蚀开裂倾向大小关系为600 ℃>550 ℃>650 ℃。825在SCW条件下的腐蚀实验表明,其腐蚀增重大致符合幂函数生长规律;而其在次临界条件下的腐蚀增重变化却呈现出先减后增的特征。

     

    Abstract: The susceptibility to stress corrosion cracking (SCC) of nickel based alloy 825 was studied in supercritical water (SCW) at 550 ℃/25 MPa, 600 ℃/25 MPa and 650 ℃/25 MPa respectively, and their general corrosion behavior was researched in supercritical water at 650 ℃/25 MPa and in subcritical water at 290 ℃/15.2 MPa respectively. The strain-stress curve obtained from slow strain rate tensile tests (SSRT) shows that the strength and elongation of alloy 825 decrease with the increase of temperature. The ex-situ scanning electron microscopy shows that the SCC susceptibility of alloy 825 is 600 ℃>550 ℃>650 ℃. The general corrosion experiment in SCW shows that the weight gain is subject to power function growth rule, while the one in subcritical water indicates the weight loss and then weight gain.

     

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