高温高压动水回路中A106Gr.B和A672Gr.B60耐冲蚀作用的研究

Study on Corrosion Resistance of A106Gr.B and A672Gr.B60 in Dynamic Water Loop With High Temperature and Pressure

  • 摘要: 碳钢和低合金钢由于Cr含量较低,易发生流动加速腐蚀,对安全产生严重影响。现阶段最先进的第三代核电技术AP1000使用Cr含量较高的A672Gr.B60代替A106Gr.B作为供水管的材料来减小流动加速腐蚀(FAC)的影响。试验采用腐蚀失重、X射线光电子能谱(XPS)、扫描电镜(SEM)和X射线能量色散谱(EDS)等方法来分析流速、碱化剂以及物质组成对A672Gr.B60和A106Gr.B的影响。经336 h的实验,结果显示A672Gr.B60较A106Gr.B具有更好的耐冲蚀性能,氧化膜更致密,不易脱落。使用乙醇胺(ETA)作为碱化剂相比于氨水能更好地降低FAC,也能使氧化膜更加致密。流速的变化会影响氧化物颗粒的分布、大小、形状,也会影响氧化膜的厚度。实验生成的氧化膜主要成分为Fe3O4

     

    Abstract: Due to the low carbon and low alloy Cr content, flow accelerates corrosion prone to have a serious impact on safety. AP1000 is the most advanced nuclear power technology in recent years. The plant used A672Gr.B60 as an alternative feed pipe to reduce the impact of flow accelerated corrosion. The impact of different flow rates, alkaline agent type and material property on A672Gr.B60 and A106Gr.B were characterized by scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDS) and X-ray photoelectronic spectroscopy (XPS). After 336 h experiments were conducted, results show that the corrosion rate of A672Gr.B60 is much lower than that of A106Gr.B, and the density of oxidation film on A672Gr.B60 is superior to A106Gr.B. Ethanolamine (ETA) as an alkaline agent is better to reduce FAC to A106Gr.B, and it also can make the oxidation film become denser. Changes in flow rate will affect the size, shape and distribution of the oxide particles, and will also affect the thickness of the oxide film. Both of two materials were composed by Fe3O4.

     

/

返回文章
返回