HTGR包覆燃料颗粒碳化硅层细晶化研究

Study of SiC Layer with Fine Grains in HTGR Coated Fuel Particles

  • 摘要: 高温气冷堆(HTGR)是能适应未来能源市场的第四代先进核反应堆堆型之一,其固有安全性的第一道保障是使用的TRISO型包覆燃料颗粒。在TRISO型燃料颗粒4层包覆结构中,SiC包覆层是承受包覆燃料颗粒内压和阻挡裂变产物释放的关键层,制备高质量SiC包覆层是核燃料领域中的重大问题和关键技术之一。本文介绍高温气冷堆燃料颗粒的基本结构,详述制备SiC包覆层的流化床-化学气相沉积过程,提出SiC层细晶化这一研究方向,并系统阐述包覆燃料颗粒SiC包覆层细晶化的优势。在细晶化SiC材料制备方法方面,系统分析SiC粉体、陶瓷、薄膜和厚膜材料的研究现状,并结合本实验室前期研究成果提出制备细晶SiC包覆层的可行制备策略。

     

    Abstract: High temperature gas-cooled reactor (HTGR) with inherent safety characteristics is considered as one of the attractive and competitive generation Ⅳ nuclear reactors in the future energy markets. Tristructural-isotropic (TRISO) coated particle fuel is the most significant safety aspect in this nuclear reactor, since it relies on the properties of the four coating layers surrounding the kernel fuel to hinder the release of harmful radioactive material. Among these layers, the silicon carbide (SiC) coating is considered the most important as it not only provides the TRISO particle with structural integrity but also retains fission products at elevated temperatures. The preparation of high quality SiC layers is one of significant issues and key technologies in nuclear fuel fabrication. The basic structure of the TRISO-coated fuel particles and the fluidized bed chemical vapor deposition (FBCVD) method to prepare SiC layers were introduced. The advantages of decreasing grain size of SiC layers were analyzed and the idea to prepare SiC layers with fine grain size was proposed. In the preparation strategies, recent research developments of fine grain SiC materials in the forms of powders, ceramics, thin films and coatings were reviewed. Based on the progresses achieved by our group, basic synthesis routes for the preparation fine grain SiC coatings were proposed.

     

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