骨粉对放射性废水中钍的吸附行为研究

Study on Adsorption of Thorium from Radioactive Wastewater onto Bone Powder

  • 摘要: 以骨粉为吸附材料,对水溶液中的Th(Ⅳ)进行吸附研究。采用X射线衍射(XRD)、红外光谱(FT-IR)和扫描电镜(SEM)表征了骨粉的理化性质。考察了溶液pH值、钍溶液浓度、接触时间、温度等对骨粉吸附钍的影响,并对骨粉吸附钍的吸附机理进行了探讨。结果表明,骨粉在pH=3时有最大吸附容量。等温吸附实验及动力学研究表明,骨粉对钍的吸附行为符合准二级动力学模型和Langmuir等温吸附模型,单分子层饱和吸附容量为482.50 mg/g。热力学研究表明,骨粉对钍的吸附是自发的吸热过程。

     

    Abstract: The bone powder was chosen as the adsorbent, and the adsorption of Th(Ⅳ) on bone powder in aqueous solution was studied. The physicochemical properties of bone powder were characterized by X-ray diffraction (XRD), infrared spectroscopy (FT-IR) and scanning electron microscope (SEM). The factors affecting the adsorption of Th(Ⅳ) in aqueous solution such as initial pH values, the initial concentrations of Th(Ⅳ), contact time and temperature were investigated by batch static adsorption experiments, and the adsorption mechanism was also discussed. The results indicate that the adsorption of Th(Ⅳ) on the bone powder is strongly dependent on pH, attaining the highest point at pH=3. The adsorption kinetics can be better described by the pseudo-second-order model, and the adsorption process can be well defined by the Langmuir isotherm model, and the maximum monolayer adsorption capacity is 482.50 mg/g. The adsorption process is feasible, spontaneous and endothermic in nature.

     

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