UO2-碳纳米管复合燃料导热性能研究

Study on Thermal Conductivity of UO2-MWNTs Composite Fuel

  • 摘要: 设计和制备了UO2-碳纳米管(MWNTs)复合燃料芯块,研究了复合燃料的导热性能,分析了影响复合燃料热导率的关键因素。结果表明:复合燃料热导率主要与MWNTs的体积含量、界面和MWNTs的长径比有关。复合燃料的热导率随MWNTs体积含量的增加而升高,当体积含量超过10%时,提升效果进一步加强;界面对复合燃料的热导率影响显著,在1 521 ℃以上,UO2会与MWNTs发生界面反应生成UC等界面相,阻碍了燃料热导率的提高。在1 450 ℃,热压烧结芯块的热导率提高25.65%,在1 650、1 700和1 750 ℃,无压烧结芯块的热导率分别提高了22.67%、20.32%和18.3%;复合燃料热导率随着MWNTs长径比的增大而升高,掺杂MWNTs的长径比分别为3×103、5×103、7×103和9×103时,燃料热导率分别提高了18.3%、19.93%、22.42%和25.09%。

     

    Abstract: The UO2-MWNTs (multi-walled carbon nanotubes) composite fuel was designed and prepared, the thermal conductivity of the composite fuel was studied, and the key factors affecting the thermal conductivity of the composite fuel were analyzed. The results show that the thermal conductivity of composite fuel is mainly related to the volume content of MWNTs, the interface and the length-to-diameter ratio of MWNTs. The thermal conductivity of composite fuel increases with MWNTs volume content. When the volume content is more than 10%, the thermal conductivity of the composite fuel is further enhanced; The phase interface of UO2 and MWNTs have a significant effect to the thermal conductivity. At above 1 521 ℃, UO2 and MWNTs react to produce UC which hinder the improvement of the thermal conductivity. At 1 450 ℃, the thermal conductivity of hot pressed sintered pellet increases by 25.65%, and at 1 650, 1 700 and 1 750 ℃, the thermal conductivities of pressureless sintered pellets increase by 22.67%, 20.32% and 18.3%. The thermal conductivity of the composite fuel increases with length-to-diameter ratio. When the length-to-diameter ratios of MWNTs are 3×103, 5×103, 7×103 and 9×103, the thermal conductivities increase by 18.3%, 19.93%, 22.42% and 25.09% respectively.

     

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