SuperLig®620用于水中90Sr含量的监测方法研究

Study on Monitoring of 90Sr in Aqueous Solution Using SuperLig®620

  • 摘要: 为实现水中90Sr的连续监测,利用SuperLig®620固相萃取颗粒从水中选择性分离和富集90Sr,并通过塑料闪烁体测量SuperLig®620色层柱上90Sr的含量。研究了0.2 mg/L Sr-0.01 mol/L HNO3介质下,90Sr在SuperLig®620色层柱上的动态平衡。结果表明,吸附平衡时90Sr在两相间的浓度呈正比,因此通过测量柱上90Sr的含量可得到水中90Sr的浓度。所建立的方法对90Sr的探测效率和最小可探测活度分别为21.3%和2.6 Bq/L,对某低放废水中90Sr的分析误差小于20%。

     

    Abstract: In order to achieve continuous monitoring of 90Sr in aqueous solution, 90Sr was firstly separated selectively and enriched by SuperLig®620 solid phase extraction beads, which was then measured in-situ using plastic scintillator. The influences of 90Sr activity on two-phase equilibrium were studied and the results show that the concentration in aqueous solution is directly proportional to that captured on the column in 0.2 mg/L Sr-0.01 mol/L HNO3 medium. So the concentration of 90Sr in aqueous solution can be analyzed by detecting 90Sr on the column. The detection efficiency and minimum detectable activity are 21.3% and 2.6 Bq/L, respectively. The concentration of 90Sr in low level radioactive waste water was analyzed using the above method and the analytical error is lower than 20%.

     

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