基于气动悬浮的高温氧化物熔体热物性测量

Thermophysical Property Measurement of High-temperature Oxide Melt by Aerodynamic Levitation

  • 摘要: 堆芯熔融物的热物性是研究反应堆严重事故进程及堆内堆外现象机理的重要基础参数。当堆芯熔化时,堆内温度达3 000 K,形成U-Zr-O-Fe多元混合物,而气动悬浮技术是优选的高温下测量堆芯熔融物基础热物性的技术。本文描述了一套基于气动悬浮和激光加热技术的密度、表面张力和黏度的测量装置,目前已实现高温氧化物密度的实验测量。装置采用收缩-扩张型锥形喷嘴悬浮球状样品,采用CO2连续激光器加热并熔化样品,采用双色红外测温仪监测样品的温度并进行激光器功率反馈控制;采用高速相机记录样品轮廓的变化,并结合图像分析法计算样品的体积,最后得到被测材料在高温下的密度。实验测量得到2 750~3 200 K范围内氧化锆熔体的密度,其在熔点(2 988 K)处的密度为4.717 g/cm3,温度系数为-7.202×10-4 g/(cm3·K)。

     

    Abstract: Thermophysical properties of molten core materials are necessary input parameters to predict the progression as well as to evacuate the risk of severe accidents in light water reactors. Thermophysical properties of corium are also needed to assess the effectiveness of mitigation strategies, such as invessel and ex-vessel melt retentions, which are preferred in advanced light water reactors. The corium contains the components of UO2, ZrO2, Zr and Fe, and the melt temperature can reach around 3 000 K. Due to the high temperature, molten corium property data are limited and very difficult to obtain so far. Aerodynamic levitation is a preferred technique to measure the thermophysical properties of high-temperature oxides. An apparatus based on aerodynamic levitation & laser heating for measurement of density, surface tension and viscosity was described in this paper. The experimental apparatus was named as ALSEE (aerodynamic levitation-laser heating installation for melt properties). ALSEE was composed of aerodynamic levitation system, laser heating system, image recording system, temperature measurement system, acoustic excitation system and data acquisition system (DAS). The first four systems and DAS were built, which were sufficient for density measurement. The acoustic excitation system under installation would be intended for the measurements of surface tension and viscosity. Powders or irregular objects could be melted into a nearly spherical sample by laser heating in a device called laser hearth melter. The laser hearth melter was made of copper and oxide samples with diameter of 24 mm could be made from it. During the actual experiment, a sample sphere was firstly levitated by a conical nozzle, then it was heated into a liquid drop by a CO2 laser, and the sample shape was recorded by a high-speed camera. A common canny edge detection algorithm was used and the least-squares fitting based on algebraic distances was performed by inverse technique. Finally, the density was calculated from the mass of the sample and the liquid drop volume derived from image post-treatments based on the ellipsoid assumption. As tests before the prototype corium, density of liquid zirconium oxide was measured to be 4.717 g/cm3 at the melting point of 2 988 K while the temperature coefficient was claimed to be -7.202×10-4 g/(cm3·K) from 2 750 K to 3 200 K.

     

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