小冷凝速率下亚微米气溶胶自然沉积实验研究

Experimental Study on Natural Deposition of Submicron Aerosols at Small Steam Condensation Rate

  • 摘要: 为了研究小型反应堆在事故后亚微米气溶胶自然沉积行为,自主搭建了实验平台并开展了小冷凝速率下的相关实验。研究中发现蒸汽份额的提升对气溶胶基础的重力沉降过程存在促进作用,压力提升存在抑制作用;泳动去除机制的贡献占比随着蒸汽冷凝速率的提升而增加;冷凝速率较小时,热泳沉积机制在泳动去除机制中的占比可忽略不计;扩散泳S/W模型的适用性提高至385 K,当蒸汽密度和压力再增加时,实验所得亚微米气溶胶的扩散泳沉降速率高于S/W模型预测结果,根据蒸汽冷凝相关理论提出了修正系数。吸湿性气溶胶更容易在蒸汽冷凝条件下被扩散蒸汽夹带去除,3种扩散泳计算模型均无法准确预测吸湿性气溶胶的沉降过程。

     

    Abstract: In order to study the natural deposition behavior of submicron aerosols at a small steam condensation rate, an experimental platform was built and the related experimental research was carried out in this paper. In the process of the experiment, the self-developed sampling pretreatment system was used to carry out the aerosol sampling analysis in the high temperature and high humidity environment. The gravity sedimentation mechanism is one of the most common removal mechanisms in natural deposition. Several gravity sedimentation experiments were carried out first, and the experiments were used as the basis for other experiments. Next, the natural deposition experiment of sub-micron aerosol was carried out at a small steam condensation rate by adjusting the steam condensation rate before distributing the aerosol. Based on the gravity sedimentation data with the same thermal parameters, the attenuation constants under the action of thermophoresis and diffusiophoresis were obtained. The results show that when there is steam in the working medium, the gravity removal effect of submicron aerosol is better than that of pure air under the same thermal conditions. The proportion of steam can promote the gravity settlement. The pressure has inhibitory effect on gravity settlement. And with the increase of pressure, the increase of steam share has a more significant effect on the increase of gravity removal rate. In the natural removal process of submicron aerosols, the proportion of removal by diffusiophoresis and thermophoresis mechanisms increase with steam condensation rate, accounting for more than 90%. Under the condition of low vapor condensation, the contribution of diffusiophoresis is great, followed by gravity deposition, and thermophoretic deposition can be ignored to a certain extent. When the steam density is low, the diffusiophoresis sedimentation rate is in good agreement with the S/W model. When the steam density increases, the experimental sedimentation rate is higher than the calculation result of the S/W model, and relevant corrections have been made. Under the same thermal parameters, the diffusiophoresis sedimentation rate of NaCl is much higher than that of TiO2, and much larger than the prediction results of the three current diffusiophoresis models.

     

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