Abstract:
Small modular lead-based reactors with features of compact design and environments of high neutron fluence and high temperature urgently require a structural-functional integrated neutron shielding material that combines good high-temperature mechanical properties and neutron shielding performance. As boron- and gadolinium-containing steels exhibit insufficiency in mechanical properties at high temperature and process-ability, this study selected GdAl
3C
3 cermet as the reinforcing phase and neutron absorber and 316L stainless steel as the matrix in order to develop a GdAl
3C
3-316L shielding material. The GdAl
3C
3-316L shielding material samples with GdAl
3C
3 additions of 0.5%, 1.5%, 3.0% and 5.0% (in weight percentage) were prepared by powder metallurgy. Their micro-structure, tensile properties at room- and high-temperature and neutron shielding performance were systematically analyzed. The results show that chromium-rich phases agglomerate in the material as the GdAl
3C
3 content increases. The formation of a dual-phase structure of ferrite and austenite is promoted in 316L matrix with the solid solution of Al. Furthermore, the GdAl
3C
3-316L samples exhibit a bimodal grain size distribution and the addition of GdAl
3C
3 refined the matrix grains. With GdAl
3C
3 addition among 1.5% to 3.0%, the material simultaneously possesses a high proportion of fine-grained regions (>82%), a relatively high proportion of high-angle grain boundaries (>92%), and an appropriate proportion of twin boundaries, achieving a better balance among fine-grain strengthening, ductility coordination, and crack deflection capability. Various
in situ formed Gd-Al-O ternary oxides are observed in 1.5%GdAl
3C
3-316L sample, including nanoscale monoclinic Gd
4Al
2O
9 precipitates, submicron simple orthorhombic GdAlO
3 precipitates, and body-centered cubic Gd
3Al
5O
12 precipitates, which are dispersed in 316L matrix. The tensile properties at room- and high-temperatures of the samples initially increase and then decrease with the increasing of GdAl
3C
3 content. The 1.5%GdAl
3C
3-316L sample demonstrates good mechanical properties with a yield strength of 696.2 MPa and 613.2 MPa, and an elongation of 22.4% and 14.9% at room temperature and 550 ℃, respectively. The SEM image of the tensile fracture surface of the sample indicates that the material as a whole exhibits ductile fracture characteristic. The neutron shielding experiments show that 3.0%GdAl
3C
3-316L and 5.0%GdAl
3C
3-316L samples achieve a thermal neutron shielding rate of 81.25% and 95.84% at a thickness of 0.9 mm, respectively. The neutron shielding performance of the material is improved with the increase of GdAl
3C
3 content. Compared to Gd-316L alloys with similar gadolinium content, the 1.5%GdAl
3C
3-316L alloy in this study exhibits a better synergy of tensile strength and plastic deformation capability, which indicates its potential for use as a structural-functional integrated neutron shielding material in lead-based reactor.