GdAl3C3含量对GdAl3C3-316L中子屏蔽材料微观组织和力学性能影响研究

Effect of GdAl3C3 Content on Micro-structure and Mechanical Property of Neutron Shielding GdAl3C3-316L Material

  • 摘要: 小型铅冷快堆具有紧凑化设计及高中子通量与高温运行环境等特点,亟需一种兼具优异高温力学和中子屏蔽性能的结构-功能一体化中子屏蔽材料。为解决传统中子屏蔽材料含硼钢和含钆钢高温力学与加工性能不足的问题,本文研究采用粉末冶金法制备了GdAl3C3添加量分别为0.5%、1.5%、3.0%和5.0%(质量分数)的GdAl3C3-316L金属基中子屏蔽材料样品,系统分析了其微观组织、室温和高温拉伸性能及中子屏蔽性能。结果表明:样品组织中原位生成多种Gd-Al-O三元氧化物并弥散分布于316L基体中。材料室温及高温拉伸性能随GdAl3C3添加量增加呈先增后降趋势,1.5%GdAl3C3-316L样品表现出较好的力学性能,550 ℃下其屈服强度为613.2 MPa,延伸率为14.9%。材料中子屏蔽性能随GdAl3C3添加量增加而提升,5.0%GdAl3C3-316L样品在0.9 mm厚度下的热中子屏蔽率达到95.84%。本文研究的GdAl3C3-316L合金作为结构-功能一体化中子屏蔽材料在小型铅冷快堆屏蔽系统中具有潜在应用前景。

     

    Abstract: Small modular lead-based reactors with features of compact design and environments of high neutron fluence and high temperature urgently require a structural-functional integrated neutron shielding material that combines good high-temperature mechanical properties and neutron shielding performance. As boron- and gadolinium-containing steels exhibit insufficiency in mechanical properties at high temperature and process-ability, this study selected GdAl3C3 cermet as the reinforcing phase and neutron absorber and 316L stainless steel as the matrix in order to develop a GdAl3C3-316L shielding material. The GdAl3C3-316L shielding material samples with GdAl3C3 additions of 0.5%, 1.5%, 3.0% and 5.0% (in weight percentage) were prepared by powder metallurgy. Their micro-structure, tensile properties at room- and high-temperature and neutron shielding performance were systematically analyzed. The results show that chromium-rich phases agglomerate in the material as the GdAl3C3 content increases. The formation of a dual-phase structure of ferrite and austenite is promoted in 316L matrix with the solid solution of Al. Furthermore, the GdAl3C3-316L samples exhibit a bimodal grain size distribution and the addition of GdAl3C3 refined the matrix grains. With GdAl3C3 addition among 1.5% to 3.0%, the material simultaneously possesses a high proportion of fine-grained regions (>82%), a relatively high proportion of high-angle grain boundaries (>92%), and an appropriate proportion of twin boundaries, achieving a better balance among fine-grain strengthening, ductility coordination, and crack deflection capability. Various in situ formed Gd-Al-O ternary oxides are observed in 1.5%GdAl3C3-316L sample, including nanoscale monoclinic Gd4Al2O9 precipitates, submicron simple orthorhombic GdAlO3 precipitates, and body-centered cubic Gd3Al5O12 precipitates, which are dispersed in 316L matrix. The tensile properties at room- and high-temperatures of the samples initially increase and then decrease with the increasing of GdAl3C3 content. The 1.5%GdAl3C3-316L sample demonstrates good mechanical properties with a yield strength of 696.2 MPa and 613.2 MPa, and an elongation of 22.4% and 14.9% at room temperature and 550 ℃, respectively. The SEM image of the tensile fracture surface of the sample indicates that the material as a whole exhibits ductile fracture characteristic. The neutron shielding experiments show that 3.0%GdAl3C3-316L and 5.0%GdAl3C3-316L samples achieve a thermal neutron shielding rate of 81.25% and 95.84% at a thickness of 0.9 mm, respectively. The neutron shielding performance of the material is improved with the increase of GdAl3C3 content. Compared to Gd-316L alloys with similar gadolinium content, the 1.5%GdAl3C3-316L alloy in this study exhibits a better synergy of tensile strength and plastic deformation capability, which indicates its potential for use as a structural-functional integrated neutron shielding material in lead-based reactor.

     

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