快堆MOX燃料中模浮动压制生坯性能与缺陷研究

Research of Property and Defect of Fast Reactor MOX Fuel Green Pellet in Floating Pressing

  • 摘要: 生坯压制成型是MOX燃料制备的关键步骤,本文采用中模浮动压制技术进行MOX燃料原料氧化铝的生坯压制和芯块烧结,对比两种氧化铝粉末的中模浮动压制性能,并研究生坯外观缺陷产生的原因和解决措施。结果表明,科密欧氧化铝生坯和煅烧氧化铝生坯的成型性和压缩性相反;随着压制压力的增加,科密欧氧化铝生坯和煅烧氧化铝生坯密度和强度逐渐增加,但压制粉末性能对生坯密度和强度的影响程度大于压制参数。生坯密度和强度与粉末性能和压制压力有关,与加压时间、降压时间和脱模维持压力无关,两种氧化铝生坯压制曲线均较好地符合黄培云双对数方程;随着压制压力的增加和脱模维持压力的减小,生坯掉盖、爆头和破碎减少;随着硬脂酸锌添加量的增加,生坯侧面划痕消失,但芯块密度逐渐降低。

     

    Abstract: Green pellet pressing is critical step in the preparation of oxide ceramic fuel that decides density, strength and microstructure of green pellets and pellets. The medium mode floating pressing properties of calcined alumina and Comeo alumina powder were compared, and the causes and solving measures of green pellets appearance defects were studied. The results show that the density of calcined alumina compact is much higher than that of Comeo alumina compact, but the strength of calcined alumina compact is much lower than that of Comeo alumina compact. The formability and compressibility of Comeo alumina and calcined alumina are opposite. With the increase of pressing pressure, the density and strength of Comeo alumina green pellets and calcined alumina green pellets gradually increase, but the influence of the properties of pressing powder on the density and strength is greater than the pressing parameters. The pressing curves of Comeo alumina green pellets and calcined alumina green pellets accord well with Huang Peiyun's double logarithm equation. Alumina is an inelastic compression in the pressing process, and there are work hardening and friction in the medium die. The density and strength of green pellets are related to powder strength, powder morphology and pressing pressure, but have nothing to do with pressing time, reducing time and demoulding pressure. With the increase of pressing pressure, the number of capping, blasting and crushing of calcined alumina green pellets decreases, and with the increase of demoulding maintenance pressure, the number of lid, blasting and crushing increases, and the degree of crushing deepens. Increasing the pressing pressure and decreasing the demoulding maintenance pressure are beneficial to reduce the defects such as lid dropping, head blasting and crushing, and when the pressure is 160 kN, macroscopic cracks appear on the surface of the green pellets. The low addition of zinc stearate makes the friction phenomenon of the medium die serious, resulting in side scratches and cracks. Zinc stearate plays the role of lubrication of the inner wall of the middle mold in the pressing stage. The sintering experiments show that the density of the pellet decreases gradually with the increase of zinc stearate addition, and the porosity of the pellet increases obviously. Zinc stearate acts as a pore-forming agent in the sintering stage. So when adding zinc stearatethe role of lubrication and pore-making should be considered at the same time.

     

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